Chromatographic Resolution Calculator | PharmacyFreak

Chromatographic Resolution Calculator

Calculate retention factor (Rf) and resolution (Rs) with step-by-step breakdown.
For TLC, HPLC, and pharma analysis
Retention factor (Rf)

Resolution (Rs)
Why resolution matters?
Rs tells us how well two analytes are separated in chromatography.
Rs > 1.5 means "baseline" (full) separation.
Rf helps identify and optimize mobile phase in TLC/HPTLC.
Typical Rf (TLC): 0.3–0.8 is ideal.

Chromatographic Resolution Calculator (Rf & Rs)

Welcome to the Chromatographic Resolution Calculator, an essential educational tool for B. Pharm students and analytical chemistry learners. This tool helps you calculate two key parameters used in Thin Layer Chromatography (TLC) and High-Performance Liquid Chromatography (HPLC):

  • Rf (Retention Factor) – Indicates how far a compound travels on a chromatogram.

  • Rs (Resolution) – Measures the separation between two peaks in a chromatogram.

How It Works

🔹 Step 1: Choose What to Calculate

You can calculate:

  • Rf value from a single compound’s travel distance.

  • Rs value from two compound retention times and peak widths.

🔹 Step 2: Enter Required Inputs

For Rf:

  • Distance moved by compound

  • Distance moved by solvent front

  • Select units: mm or cm

For Rs:

  • Retention Time of Peak 1 (tR₁)

  • Retention Time of Peak 2 (tR₂)

  • Peak Widths at Base: W₁ and W₂

  • Select time units: sec or min

🔹 Step 3: Click “Calculate”

The calculator will:

  • Display calculated value (Rf or Rs)

  • Show a dynamic TLC sketch or Resolution Bar

  • Explain the formula used with substituted values

Features & Output

Rf Calculator Outputs

  • Final Rf value (0 to 1)

  • Visual TLC sketch (solvent front, compound dot, baseline)

  • Ideal Range Message (e.g., “Rf between 0.3 – 0.7 is ideal”)

📈 Rs Calculator Outputs

  • Final Resolution (Rs) value

  • Color-coded Resolution Bar with ranges:

    • Red: Poor (< 1)

    • Yellow: Borderline (1.0 – 1.5)

    • Green: Good (> 1.5)

🖼 Visual Enhancements

  • Responsive Charts powered by Chart.js

  • Real-time updates after calculation

  • Export Options:

    • PNG (graph only)

    • PDF (full result card + visual)

Educational Value

This tool not only calculates but teaches:

  • Step-by-step formula application

  • Tooltip definitions for each field:

    • What is Rf?

    • Why is Rs important in separation science?

  • Ideal Rf and Rs interpretation ranges

  • Clear understanding of TLC and HPLC outputs

Why This Calculator Is Essential

Understanding chromatographic resolution is key in:

  • Drug purity analysis

  • Pharmacopoeial standards

  • HPLC method validation

  • TLC fingerprinting and compound identification

This tool reinforces core analytical concepts and enhances laboratory calculation accuracy.

Why This Calculator Is Essential

Understanding chromatographic resolution is key in:

  • Drug purity analysis

  • Pharmacopoeial standards

  • HPLC method validation

  • TLC fingerprinting and compound identification

This tool reinforces core analytical concepts and enhances laboratory calculation accuracy.